A ONE-STEP CONTROL OF 4 STEREOGENIC CENTERS DURING THE SAKURAI REACTION OF 1,8-BIS(TRIMETHYLSILYL)OCTA-2,6-DIENE (BISTRO) TO ALPHA,BETA-ENONES

Authors
PELLISSIER H SANTELLI M
Citation
H. Pellissier et M. Santelli, A ONE-STEP CONTROL OF 4 STEREOGENIC CENTERS DURING THE SAKURAI REACTION OF 1,8-BIS(TRIMETHYLSILYL)OCTA-2,6-DIENE (BISTRO) TO ALPHA,BETA-ENONES, Journal of the Chemical Society, Chemical Communications, (7), 1994, pp. 827-828
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
7
Year of publication
1994
Pages
827 - 828
Database
ISI
SICI code
0022-4936(1994):7<827:AOCO4S>2.0.ZU;2-N
Abstract
The titanium tetrachloride mediated addition reaction of 1,8-bis(trime thylsilyl)octa-2,6-diene (BISTRO) with open-chain conjugated enones af fords syn-anti-syn-4,7-divinyldecane-1,10-diones with a very high dias tereoselectivity.