THE IMPORTANCE OF PERIPHERAL ASSOCIATION FOR VITAMIN-B12 CATALYZED METHYLMALONYL-SUCCINYL-REARRANGEMENT

Authors
WOLLEBGYGI A DARBRE T SILJEGOVIC V KEESE R
Citation
A. Wollebgygi et al., THE IMPORTANCE OF PERIPHERAL ASSOCIATION FOR VITAMIN-B12 CATALYZED METHYLMALONYL-SUCCINYL-REARRANGEMENT, Journal of the Chemical Society, Chemical Communications, (7), 1994, pp. 835-836
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
7
Year of publication
1994
Pages
835 - 836
Database
ISI
SICI code
0022-4936(1994):7<835:TIOPAF>2.0.ZU;2-2
Abstract
The rearrangement of methylmalonyl to succinyl radicals becomes an eff icient process, when the reaction is performed in a protic solvent wit h both the vitamin B-12-derived catalyst and the substrate carrying a C-18 instead of a C2 alkyl chain.