MOLECULAR-STRUCTURE OF [MNIIIL2]- [H2L = N-(3,5-DICHLORO-2-HYDROXYBENZYL)GLYCINE] - EVIDENCE FOR A PSEUDO-JAHN-TELLER COMPRESSION

Authors
SHONGWE MS MIKURIYA M AINSCOUGH EW BRODIE AM
Citation
Ms. Shongwe et al., MOLECULAR-STRUCTURE OF [MNIIIL2]- [H2L = N-(3,5-DICHLORO-2-HYDROXYBENZYL)GLYCINE] - EVIDENCE FOR A PSEUDO-JAHN-TELLER COMPRESSION, Journal of the Chemical Society, Chemical Communications, (7), 1994, pp. 887-888
Citations number
22
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
7
Year of publication
1994
Pages
887 - 888
Database
ISI
SICI code
0022-4936(1994):7<887:MO[[=N>2.0.ZU;2-M
Abstract
Reaction of 2 equivalents of the deprotonated ligand, L2-, with mangan ese(II) under ambient conditions involves one-electron oxidation of th e latter to afford the title complex; a single-crystal X-ray diffracti on study of this heteroleptic complex has shown the Mn(III) ion to be in a compressed rhombic octahedral environment in accordance with a ps eudo-Jahn-Teller compression.