THE 4-ELECTRON OXIDATION OF MESO-OCTAETHYLPORPHYRINOGEN VIA A METAL-MEDIATED DEALKYLATION PROCESS - FORMATION OF [RUL(PHCN)2] [H2L = 5,15-DIHYDRO-5,5,10,15,15,20-HEXAETHYLPORPHYRIN]

Authors
PIARULLI U FLORIANI C CHIESIVILLA A RIZZOLI C
Citation
U. Piarulli et al., THE 4-ELECTRON OXIDATION OF MESO-OCTAETHYLPORPHYRINOGEN VIA A METAL-MEDIATED DEALKYLATION PROCESS - FORMATION OF [RUL(PHCN)2] [H2L = 5,15-DIHYDRO-5,5,10,15,15,20-HEXAETHYLPORPHYRIN], Journal of the Chemical Society, Chemical Communications, (7), 1994, pp. 895-896
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
7
Year of publication
1994
Pages
895 - 896
Database
ISI
SICI code
0022-4936(1994):7<895:T4OOMV>2.0.ZU;2-6
Abstract
A four-electron oxidation of meso-octaethylporphyrinogen (H4L') involv ing the dealkylation of two meso carbons has been observed in the reac tion between [Ru(Cl)2(PhCN)4] and [Li4L'(THF)4] leading to [RuL(PhCN)2 ] which contains two hemiporphyrin fragments joined by two sp3 carbons , as shown by an X-ray analysis.