The results of an ab initio quantum chemical study, carried out largel
y at the MP2 level of theory, are reported for the trimethylamine-hydr
ogen chloride complex. The resulting geometry, harmonic frequencies an
d properties such as dipole moment and electric field gradients at the
Cl and N nuclei are compared with those of the parent monomers as wel
l as those of the trimethyl-ammonium ion. The computed N...Cl distance
, intermolecular stretching frequency and field gradients agree with e
xperiment. The asymmetric NHCl stretch is found to be quite anharmonic
and consequently vibrational averaging with respect to that mode has
a significant effect on the dipole moment and electric field gradients
. The calculated structure and frequencies point to a large degree of
proton transfer and hence ionic character. This is confirmed by an ana
lysis of the SCF binding energy by the constrained spatial orbital var
iation method as well as the results of population analyses that also
suggest significant covalency.