STRUCTURE OF METAL-METAL OXIDE PD-V2O5 AL2O3 CATALYST FOR COMPLETE OXIDATION OF HYDROCARBONS

Authors
VASSILEVA M MOROZ E DANCHEVA S USHAKOV V ANDREEV A
Citation
M. Vassileva et al., STRUCTURE OF METAL-METAL OXIDE PD-V2O5 AL2O3 CATALYST FOR COMPLETE OXIDATION OF HYDROCARBONS, Applied catalysis. A, General, 112(2), 1994, pp. 141-148
Citations number
20
Categorie Soggetti
Chemistry Physical","Environmental Sciences
Journal title
Applied catalysis. A, General → ACNP
ISSN journal
0926860X
Volume
112
Issue
2
Year of publication
1994
Pages
141 - 148
Database
ISI
SICI code
0926-860X(1994)112:2<141:SOMOPA>2.0.ZU;2-E
Abstract
A Pd-V2O5/Al2O3 catalyst system was studied by means of X-ray diffract ion methods, chemical analysis and electron spin resonance spectroscop y. Under working conditions of the reaction of complete oxidation of b enzene, the following phases were found: beta-NaxV2O5, theta-Al0.33V2O 5 and Al0.07(3+) V0.07(5+) V1.86(4+) O4. An efficient delocalization o f electrons between clustered V4+ ions in these phases facilitates the electronic transitions in the redox steps of the catalytic oxidation.