THE SELECTIVE MONOHALOGENATION OF DIHYDRO-SILANE AND TRIHYDROSILANE

Authors
GANSLE PB GRUBER BC JARVIS JT SLAITAS A DEJESUS SM DEJESUS K
Citation
Pb. Gansle et al., THE SELECTIVE MONOHALOGENATION OF DIHYDRO-SILANE AND TRIHYDROSILANE, Microchemical journal, 55(2), 1997, pp. 222-234
Citations number
25
Categorie Soggetti
Chemistry Analytical
Journal title
Microchemical journal → ACNP
ISSN journal
0026265X
Volume
55
Issue
2
Year of publication
1997
Pages
222 - 234
Database
ISI
SICI code
0026-265X(1997)55:2<222:TSMODA>2.0.ZU;2-F
Abstract
The selective monohalogenation of dihexylsilane by a number of oxidant s was studied. The most selective oxidant was found to be N-bromosucci nimide, NBS, yielding products of monobromination with greater than 50 :1 selectivity. Various degrees of monoselectivity were found in the b romination of other differentially substituted dihydro- and trihydrosi lanes by NBS. (C) 1997 Academic Press.