BARRIERS TO ENERGY MIGRATION IN MIXED-LIGAND ZINC(II) COMPLEXES

Authors
BURT JA CROSBY GA
Citation
Ja. Burt et Ga. Crosby, BARRIERS TO ENERGY MIGRATION IN MIXED-LIGAND ZINC(II) COMPLEXES, Chemical physics letters, 220(6), 1994, pp. 493-496
Citations number
6
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
220
Issue
6
Year of publication
1994
Pages
493 - 496
Database
ISI
SICI code
0009-2614(1994)220:6<493:BTEMIM>2.0.ZU;2-5
Abstract
Spectroscopic investigations of Zn(4-Cl-PhS)2(dmphen) (4-Cl-PhS=anion of 4-chlorobenzenethiol; dampen=2,9-dimethyl- 1, 10-phenanthroline) in the p2(1)/N and p2(1)/C crystal phases and in polymethylmethacrylate (PMMA) are reported. The results demonstrate the existence of an intra molecular barrier to energy migration between 3pipi and ligand-to-lig and charge-transfer levels.