DEHYDROGENATION OF ALPHA-AMINO-ACIDS CHELATED TO A CO(III) ION YIELDING ALPHA-IMINO ACIDATO COMPLEXES

Authors
YAMAGUCHI M SABURI M YOSHIKAWA S YAMAGISHI T
Citation
M. Yamaguchi et al., DEHYDROGENATION OF ALPHA-AMINO-ACIDS CHELATED TO A CO(III) ION YIELDING ALPHA-IMINO ACIDATO COMPLEXES, Bulletin of the Chemical Society of Japan, 67(5), 1994, pp. 1341-1347
Citations number
51
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
67
Issue
5
Year of publication
1994
Pages
1341 - 1347
Database
ISI
SICI code
0009-2673(1994)67:5<1341:DOACTA>2.0.ZU;2-K
Abstract
The oxidation of the alpha-amino acidato cobalt(III) complexes with 2, 3,2-tet (=3,7-diazanonane-1,9-diamine) or its derivative, where amino acidate ligand was phenylglycinate, alaninate, valinate N-methylalanin ate, or prolinate, by potassium permanganate was achieved to yield the corresponding alpha-imino acidato complexes, [Co(III){N(R1)=C(R2)CO2} (N4)]2+.