Angular correlation of two-photon annihilation radiation (ACAR) measur
ements have been performed to study the effect of interstitial impurit
ies (O, C and D) n positronium (Ps) formation in irradiation-induced v
oids of vanadium. It has been observed that Ps formation is sensitivel
y affected by doping with the interstitial impurities, irradiation dos
e, irradiation temperature, and also by post-irradiation annealing. Th
e Ps component intensity is found to be related to segregation of the
interstitial impurities and provides a new experimental method to stud
y void surfaces.