SB-121 AND I-127 MOSSBAUER SPECTROSCOPIC STUDY ON SB-I HYPERVALENT BONDS IN TRIGONAL BIPYRAMIDAL ANTIMONY(V) COMPLEXES

Authors
TAKEDA M TAKAHASHI M YANAGIDA Y KOJIMA S AKIBA KY ITO Y
Citation
M. Takeda et al., SB-121 AND I-127 MOSSBAUER SPECTROSCOPIC STUDY ON SB-I HYPERVALENT BONDS IN TRIGONAL BIPYRAMIDAL ANTIMONY(V) COMPLEXES, Hyperfine interactions, 84(1-4), 1994, pp. 439-446
Citations number
24
Categorie Soggetti
Physics, Atomic, Molecular & Chemical","Physics, Nuclear","Physics, Condensed Matter
Journal title
Hyperfine interactions → ACNP
ISSN journal
03043843
Volume
84
Issue
1-4
Year of publication
1994
Pages
439 - 446
Database
ISI
SICI code
0304-3843(1994)84:1-4<439:SAIMSS>2.0.ZU;2-R
Abstract
Both Sb-121 and I-127 Mossbauer parameters at 20 K were obtained for s ix organoantimony(V) complexes, having trigonal bipyramidal geometry a round the antimony atoms. Characteristics of the apical Sb-I hypervale nt bonds were deduced from the above parameters and also from the Sb-1 21 Mossbauer parameters of eight trigonal bipyramidal antimony complex es with other halogen atoms than iodine.