An investigation of twin structures in NdP5O14 single crystals has bee
n undertaken using white-beam synchrotron x-ray topography. The so-cal
led a-type twins along the a axis are clearly revealed in the topograp
hs. The displacements of the images that arise from the twins are dire
ctly measured in different topographs. With the measured values, the m
onoclinic distortion angle delta(delta = beta-90-degrees) is calculate
d, which is in good agreement with the unit cell parameters. A fine-be
am Laue diffraction pattern of the twin has also been taken which is w
ell consistent with its simulation. From these results, the twin struc
tures of NdP5O14 are discussed.