Ij. Jeon et al., STUDY OF INTERDIFFUSION IN PD CU MULTILAYERED FILMS BY AUGER DEPTH PROFILING/, Journal of applied physics, 75(12), 1994, pp. 7825-7828
In thin films, diffusion phenomena play an important role for the grow
th process, and in the understanding of the mechanical, electrical and
magnetic properties. The change in the concentration profile due to t
he interdiffusion by annealing was investigated using Auger electron s
pectroscopy depth-profiling technique on Pd/Cu multilayered films. It
was observed that the initial concentration distributions, which were
almost rectangular in the unheated samples, were changed into sinusoid
al ones in the annealed films at various temperatures. The concentrati
on-independent interdiffusion coefficients were calculated from the am
plitudes of sinusoidal distributions. The activation energy was determ
ined to be 1.66+/-0.23 eV from the Arrhenius plot. The concentration-d
ependent interdiffusivity at 150-degrees-C was also estimated using Bo
ltzmann-Matano method.