CHIRAL ACYCLIC NITRONE BEARING PROTECTED VICINAL DIOL CONTROLLER PROVIDING SINGLE PI(C=N)-FACE IN [3+2] CYCLOADDITION REACTIONS

Authors
SAITO S ISHIKAWA T KISHIMOTO N KOHARA T MORIWAKE T
Citation
S. Saito et al., CHIRAL ACYCLIC NITRONE BEARING PROTECTED VICINAL DIOL CONTROLLER PROVIDING SINGLE PI(C=N)-FACE IN [3+2] CYCLOADDITION REACTIONS, Synlett, (4), 1994, pp. 282-284
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
4
Year of publication
1994
Pages
282 - 284
Database
ISI
SICI code
0936-5214(1994):4<282:CANBPV>2.0.ZU;2-T
Abstract
Acyclic chiral (Z)-nitrone (4) bearing the protected vicinal diol cont roller has been developed with the intention of shielding one of its p i-(C=N) diastereofaces. The intermolecular [3+2] cycloaddition reactio ns of 4 with various olefins resulted in perfect discrimination of the nitrone faces though that of the olefins depended on their structures .