RADICAL-INDUCED RING-OPENING OF 2-(BROMOMETHYL)AZIRIDINES

Authors
DEKIMPE N DESMAELE D BOGAERT P
Citation
N. Dekimpe et al., RADICAL-INDUCED RING-OPENING OF 2-(BROMOMETHYL)AZIRIDINES, Synlett, (4), 1994, pp. 287-288
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
4
Year of publication
1994
Pages
287 - 288
Database
ISI
SICI code
0936-5214(1994):4<287:RRO2>2.0.ZU;2-S
Abstract
2-Aziridinylmethyl radicals were conveniently generated from 2-(bromom ethyl)aziridines and tributyltin hydride in benzene. Radical-induced r ing opening of the latter aziridines afforded allylamines, indicative of the aza-analogue of the rearrangement of cyclopropylmethyl radicals (carbon analogue) and 2-oxiraylmethyl radicals (oxygen analogue).