NOVEL COORDINATION PATTERN OF DITHIOPHOSPHORUS LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURE OF (DIPHENYLPHOSPHINODITHIOATO)PHENYLTELLURIUM(II), PHTES2PPH2 - SUPRAMOLECULAR ASSOCIATION THROUGH MONODENTATE BICONNECTIVE DITHIOPHOSPHORUS LIGANDS

Authors
SILVESTRU A HAIDUC I EBERT KH BREUNIG HJ
Citation
A. Silvestru et al., NOVEL COORDINATION PATTERN OF DITHIOPHOSPHORUS LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURE OF (DIPHENYLPHOSPHINODITHIOATO)PHENYLTELLURIUM(II), PHTES2PPH2 - SUPRAMOLECULAR ASSOCIATION THROUGH MONODENTATE BICONNECTIVE DITHIOPHOSPHORUS LIGANDS, Inorganic chemistry, 33(7), 1994, pp. 1253-1254
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
7
Year of publication
1994
Pages
1253 - 1254
Database
ISI
SICI code
0020-1669(1994)33:7<1253:NCPODL>2.0.ZU;2-7
Abstract
A novel coordination mode for a dithiophosphorus ligand is found in th e structure of (diphenylphosphinodithioato)phenyltellurium(II), PhTeS2 PPh2. It consists of monomeric units self-assembled into a supramolecu lar chain through secondary Te...S interactions (3.3383 angstrom). The dithio ligand acts as a monodentate biconnective bridge, and is bonde d through only one of its sulfur atoms to two tellurium atoms. This co ordination pattern has not been observed before in any metal compound containing dithiophosphorus ligands.