THE NONASODIUM SALT OF THE TRINIOBIUM-SUBSTITUTED POLYOXOANION P2W15NB3O62(9-) - A WATER-SOLUBLE, READILY CRYSTALLIZED FORM OF THIS DAWSON-BASED SOLUBLE METAL-OXIDE ORGANOMETALLICS-SUPPORT SYSTEM

Authors
NOMIYA K KANEKO M KASUGA NC FINKE RG POHL M
Citation
K. Nomiya et al., THE NONASODIUM SALT OF THE TRINIOBIUM-SUBSTITUTED POLYOXOANION P2W15NB3O62(9-) - A WATER-SOLUBLE, READILY CRYSTALLIZED FORM OF THIS DAWSON-BASED SOLUBLE METAL-OXIDE ORGANOMETALLICS-SUPPORT SYSTEM, Inorganic chemistry, 33(7), 1994, pp. 1469-1472
Citations number
47
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
33
Issue
7
Year of publication
1994
Pages
1469 - 1472
Database
ISI
SICI code
0020-1669(1994)33:7<1469:TNSOTT>2.0.ZU;2-P
Abstract
The preparation of the Dawson-type heteropolyoxoanion P2W15Nb3O629- as its water-soluble sodium salt, Na9P2W15Nb3O62.23H2O, is described. Th e title compound is obtained on up to a 13-g scale as an analytically pure, homogeneous white solid in 61% yield. It was characterized by a complete elemental analysis, TG/DTA, IR spectroscopy, and multinuclear P-31 and W-183 NMR spectroscopy.