INTERATOMIC DISTANCES FOR SOME FIRST ROW TRANSITION ELEMENT DICHLORIDES ISOLATED IN CRYOGENIC MATRICES USING X-RAY-ABSORPTION FINE-STRUCTURE SPECTROSCOPY

Authors
BEATTIE IR SPICER MD YOUNG NA
Citation
Ir. Beattie et al., INTERATOMIC DISTANCES FOR SOME FIRST ROW TRANSITION ELEMENT DICHLORIDES ISOLATED IN CRYOGENIC MATRICES USING X-RAY-ABSORPTION FINE-STRUCTURE SPECTROSCOPY, The Journal of chemical physics, 100(12), 1994, pp. 8700-8705
Citations number
30
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
100
Issue
12
Year of publication
1994
Pages
8700 - 8705
Database
ISI
SICI code
0021-9606(1994)100:12<8700:IDFSFR>2.0.ZU;2-C
Abstract
X-ray absorption fine structure (XAFS) data for several 3d transition metal dichlorides isolated in nitrogen, argon, or methane matrices hav e been collected and analyzed. The bond lengths obtained are in reason able agreement with those from vapor phase electron diffraction. The r esults are briefly discussed with reference to Badger's rule extended to triatomics.