OPTICAL STUDY OF THE ELECTRONIC-STRUCTURE AND ELECTRON MOLECULAR VIBRATIONAL COUPLING IN A NOVEL ORGANIC SUPERCONDUCTOR KAPPA-(BEDT-TTF)2CU[N(CN)2]CL0.5BR0.5

Citation
Oo. Drozdova et al., OPTICAL STUDY OF THE ELECTRONIC-STRUCTURE AND ELECTRON MOLECULAR VIBRATIONAL COUPLING IN A NOVEL ORGANIC SUPERCONDUCTOR KAPPA-(BEDT-TTF)2CU[N(CN)2]CL0.5BR0.5, Synthetic metals, 64(1), 1994, pp. 17-26
Citations number
33
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Mining
Journal title
ISSN journal
03796779
Volume
64
Issue
1
Year of publication
1994
Pages
17 - 26
Database
ISI
SICI code
0379-6779(1994)64:1<17:OSOTEA>2.0.ZU;2-2
Abstract
Reflectance spectra of a new ambient-pressure superconductor, kappa-(B EDT-TTF)2Cu[N(CN)2]Cl0.5Br0.5 (T(c) = 11.3 K), where BEDT-TTF is bis(e thylenedithio)tetrathiafulvalene, are measured in the range from 750 t o 5500 cm-1 and from 9000 to 40 000 cm-1 for different polarizations. The detailed analysis of the infrared conductivity, obtained after a K ramers-Kronig transformation, is performed in the framework of the app roach, based on the 'phase phonons' theory of M.J. Rice, with the help of special transformation of the experimental data. Parameters of the electronic subsystem and electron-molecular vibration coupling are de termined. The determined 'total' dimensionless coupling constant (lamb da) is compared with those of the organic super conductors kappa-(BEDT -TTF)2Cu(NCS)2 (T(c) = 10.4 K) and (BEDT-TTF)4Hg2.89Br8 (T(c) = 4.3 K) . It is found that a larger lambda produces a larger T(c) in accordanc e with the known Bardeen-Cooper-Schriffer formula for T(c).