DEVELOPMENT OF A SURFACE-ACOUSTIC-WAVE GAS SENSOR FOR ORGANOSPHOSPHORUS NERVE AGENTS EMPLOYING LANTHANIDE COMPOUNDS AS THE CHEMICAL INTERFACE

Citation
Ms. Nieuwenhuizen et Jln. Harteveld, DEVELOPMENT OF A SURFACE-ACOUSTIC-WAVE GAS SENSOR FOR ORGANOSPHOSPHORUS NERVE AGENTS EMPLOYING LANTHANIDE COMPOUNDS AS THE CHEMICAL INTERFACE, Talanta, 41(3), 1994, pp. 461-472
Citations number
43
Journal title
Talanta
ISSN journal
00399140 → ACNP
Volume
41
Issue
3
Year of publication
1994
Pages
461 - 472
Database
ISI
SICI code
0039-9140(1994)41:3<461:DOASGS>2.0.ZU;2-Z
Abstract
The results of a study dealing with surface acoustic wave gas sensors for organophosphorus compounds such as nerve agents are described. Sev eral lanthanum coordination compounds were applied as the chemical int erface. The various sensors prepared were challenged with both the ner ve agent sarin and the simulant dimethyl methylphosphonate. Many aspec ts were studied. such as sensitivity, selectivity. reversibility and r esponse rate as well as the effect of temperature and structural featu res. Detection limits down to 0.1 ppm were found. Response rates requi re further improvement. Degradation phenomena were observed which in s ome cases yielded irreversible responses. The selectivity for organoph osphorus compounds was found to be promising.