Ms. Nieuwenhuizen et Jln. Harteveld, DEVELOPMENT OF A SURFACE-ACOUSTIC-WAVE GAS SENSOR FOR ORGANOSPHOSPHORUS NERVE AGENTS EMPLOYING LANTHANIDE COMPOUNDS AS THE CHEMICAL INTERFACE, Talanta, 41(3), 1994, pp. 461-472
The results of a study dealing with surface acoustic wave gas sensors
for organophosphorus compounds such as nerve agents are described. Sev
eral lanthanum coordination compounds were applied as the chemical int
erface. The various sensors prepared were challenged with both the ner
ve agent sarin and the simulant dimethyl methylphosphonate. Many aspec
ts were studied. such as sensitivity, selectivity. reversibility and r
esponse rate as well as the effect of temperature and structural featu
res. Detection limits down to 0.1 ppm were found. Response rates requi
re further improvement. Degradation phenomena were observed which in s
ome cases yielded irreversible responses. The selectivity for organoph
osphorus compounds was found to be promising.