STRUCTURE AND REACTIONS OF O-4-DIPHENYLPHOSPHINO-2-PHENYL-1,3,2-DIOXABORINANE

Authors
NIKONOV GN BALUEVA AS KARASIK AA LITVINOV IA PROKHOROVA SR KATAEVA ON
Citation
Gn. Nikonov et al., STRUCTURE AND REACTIONS OF O-4-DIPHENYLPHOSPHINO-2-PHENYL-1,3,2-DIOXABORINANE, Heteroatom chemistry, 5(1), 1994, pp. 43-49
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Heteroatom chemistry → ACNP
ISSN journal
10427163
Volume
5
Issue
1
Year of publication
1994
Pages
43 - 49
Database
ISI
SICI code
1042-7163(1994)5:1<43:SAROO>2.0.ZU;2-N
Abstract
The crystal structure of o-4-diphenylphosphino-2-phenyl-1,3,2-dioxabor inane 1 indicates the occurrence of an interaction between the pi-syst ems of the 1,3,2-dioxaborinane ring and the appropriate phenyl group o f the diphenylphosphino group. Complexes of compound 1 with PtCl2, PdC l2, and Cul were synthesized. Compound 1 and its complexes are readily hydrolyzed in solution to give diphenylphosphine and its correspondin g complexes (NMR).