INFLUENCE OF NONMESOGENIC IMPURITIES ON A NEMATIC TO ISOTROPIC-PHASE TRANSITION

Authors
Citation
Pk. Mukherjee, INFLUENCE OF NONMESOGENIC IMPURITIES ON A NEMATIC TO ISOTROPIC-PHASE TRANSITION, Liquid crystals, 22(3), 1997, pp. 239-243
Citations number
31
Categorie Soggetti
Crystallography
Journal title
ISSN journal
02678292
Volume
22
Issue
3
Year of publication
1997
Pages
239 - 243
Database
ISI
SICI code
0267-8292(1997)22:3<239:IONIOA>2.0.ZU;2-0
Abstract
Non-mesomorphic solutes depress the normal nematic-isotropic transitio n temperature in liquid crystals. When non-mesomorphic solutes are add ed to a nematic liquid crystal, the nematic-isotropic transition tempe rature is depressed and a two phase region is formed due to the presen ce of impurities of the solutes. The present paper explains the format ion of this two phase region by the Landau-de Gennes phenomenological theory, which agrees fairly well with the experimental observations. W e also note that this two phase region indicates the tricritical behav iour of the nematic-isotropic phase transition and the phase diagram n ear the tricritical point is also obtained.