The two-dimensional profiles of etched grooves have been calculated as
a function of the size of masks and the ion flux of bombarding ions.
The model includes processes of adsorption of chemically active specie
s arriving from plasma, heterogeneous chemical reactions (formation vo
latile compounds on the surface), thermal desorption, physical sputter
ing, activation of surface atoms by the bombarding ions and ion beam a
ctivated desorption. Special interest is concentrated on the etching a
nisotropy, lateral etching and aspect ratio with dependence on the siz
e of mask. It is shown that ion irradiation changes etching kinetics a
nd etching anisotropy. The main role of ions is related to the activat
ion of heterogeneous reactions. It is shown that the profiles of the e
tched grooves can be modified by changing irradiation conditions and g
eometry of masks. Calculated results are qualitatively in good corresp
ondance with ones obtained experimentally.