SYNTHESIS, CHARACTERIZATION, AND REACTIVITY TOWARD NICKEL(II) OF THE NEW SATURATED 14-MEMBERED P2S2 MACROCYCLES IPHENYL-1,8-DIPHOSPHA-4,12-DITHIA-CYCLOTETRADECANE AND IPHENYL-1,8-DIPHOSPHA-4,12-DITHIA-CYCLOTETRADECANE

Authors
MUNOZ JA ESCRICHE L CASABO J PEREZJIMENEZ C KIVEKAS R SILLANPAA R
Citation
Ja. Munoz et al., SYNTHESIS, CHARACTERIZATION, AND REACTIVITY TOWARD NICKEL(II) OF THE NEW SATURATED 14-MEMBERED P2S2 MACROCYCLES IPHENYL-1,8-DIPHOSPHA-4,12-DITHIA-CYCLOTETRADECANE AND IPHENYL-1,8-DIPHOSPHA-4,12-DITHIA-CYCLOTETRADECANE, Inorganic chemistry, 36(5), 1997, pp. 947
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
5
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:5<947:SCARTN>2.0.ZU;2-1
Abstract
The new saturated 14-membered P2S2 macrocycle 1,8-diphenyl-1,8-diphosp ha-4,12-dithiacyclot (14P(2)S(2)) has been synthesized and the cis- an d transisomers have been isolated and characterized. The complexing be havior of these two isomers toward Ni(II) has been tested, and the cry stal structure of the [Ni(trans-14P(2)S(2))(CH3CH)] (ClO4)(2) complex has been solved.