SYNTHESIS AND X-RAY STRUCTURE OF THE MONONUCLEAR 9-COORDINATE GADOLINIUM(III) HYDROGEN OXYDIACETATE [GD(C4H5O5)(3)]CENTER-DOT-C4H6O5-CENTER-DOT-H2O

Authors
BAGGIO R GARLAND MT PEREC M
Citation
R. Baggio et al., SYNTHESIS AND X-RAY STRUCTURE OF THE MONONUCLEAR 9-COORDINATE GADOLINIUM(III) HYDROGEN OXYDIACETATE [GD(C4H5O5)(3)]CENTER-DOT-C4H6O5-CENTER-DOT-H2O, Inorganic chemistry, 36(5), 1997, pp. 950
Citations number
29
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
5
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:5<950:SAXSOT>2.0.ZU;2-9
Abstract
A new mononuclear gadolinium(III) complex [Gd(Hoda)(3)]. H(2)Oda . H2O (Koda = HO2CCH2OCH2CO2-) has been isolated from the reaction of Gd2O3 With oxydiacetic acid in aqueous solution. A single-crystal X-ray stu dy features the nine-coordinate GdO9 core in a distorted tricapped tri gonal-prism environment. The top and bottom triangles are defined by t hree carboxylate and three carbonyl oxygen atoms, respectively, and th e capping positions, by three ether oxygens of three tridentate Hoda l igands.