METHYL TRANSFER FROM NITROGEN TO COBALT - MODEL FOR THE B-12-DEPENDENT METHYL TRANSFER ENZYMES

Authors
PRATT JM NORRIS PR HAMZA MSA BOLTON R
Citation
Jm. Pratt et al., METHYL TRANSFER FROM NITROGEN TO COBALT - MODEL FOR THE B-12-DEPENDENT METHYL TRANSFER ENZYMES, Journal of the Chemical Society, Chemical Communications, (11), 1994, pp. 1333-1334
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
11
Year of publication
1994
Pages
1333 - 1334
Database
ISI
SICI code
0022-4936(1994):11<1333:MTFNTC>2.0.ZU;2-N
Abstract
The Co atom can be methylated by reaction of the Co-I cobalamin with t he PhNMe(3+) ion in aqueous solution at 25 degrees C at a pH-independe nt rate (pH 4-10) with the second-order rate constant k(2) = 2 x 10(-3 ) dm(3) mol(-1) s(-1).