A NOVEL ASYMMETRIC DESYMMETRISATION OF MESO-CYCLOPENTANE-1,2-DIOL VIADIASTEREOSELECTIVE BETA-ELIMINATION OF CHIRAL ALPHA-ARYLSULFINYL ACETALS

Authors
MAEZAKI N SOEJIMA M TAKEDA M SAKAMOTO A TANAKA T IWATA C
Citation
N. Maezaki et al., A NOVEL ASYMMETRIC DESYMMETRISATION OF MESO-CYCLOPENTANE-1,2-DIOL VIADIASTEREOSELECTIVE BETA-ELIMINATION OF CHIRAL ALPHA-ARYLSULFINYL ACETALS, Journal of the Chemical Society, Chemical Communications, (11), 1994, pp. 1345-1346
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
11
Year of publication
1994
Pages
1345 - 1346
Database
ISI
SICI code
0022-4936(1994):11<1345:ANADOM>2.0.ZU;2-L
Abstract
meso-Cyclopentane-1,2-diol was differentiated via diastereoselective C -O bond fission of the acetal utilising the anion stabilised by a neig hbouring chiral sulfinyl group to provide the chiral alcohol.