We have investigated the details of the growth of electron-beam deposi
ted molybdenum and silicon layers and the effect of ion-beam bombardme
nt on the morphology and interface smoothness of those layers. Using i
n-situ X-ray reflectivity, theta-2theta reflectivity scans, Auger Elec
tron Spectroscopy (AES) and Transmission Electron Microscopy (TEM) we
find that a reduction in both Mo and Si surface roughness can occur as
a result of the ion-beam bombardment. However, the overall smoothing
effect is limited by interface mixing at the underlying interface and
it is also dependent on the deposition morphology for Mo layers. When
depositing multilayers with 10 periods of 6 nm we find a large (factor
4) improvement of the reflectivity as a result of the ion-beam bombar
dment. Our best results, obtained by polishing all Si layers after gro
wth with 300 eV Kr+ ions, give a roughness of 0.3 nm for the Mo-on-Si
interfaces and less than 0.5 nm for Si-on-Mo interfaces. Cross-section
TEM pictures confirm the observations qualitatively.