The general expression of the drift velocity (as well as the related c
onductivity tensor) of atomic ions in atomic gases in static electric
and magnetic fields is obtained under the hypothesis that the ion mass
is sufficiently greater than the neutral mass (quasi-Rayleigh gas). T
he starting point of the theory is an appropriate approximate (differe
ntial) form of the Boltzmann equation. The results and their limits of
validity are discussed and extended to the more general case in which
the ions move in gas mixtures. In the light of these results, the alt
ernative non-rigorous ''momentum-transfer theory'' is analysed and its
inaccuracies and drawbacks are pointed out.