Yj. Zhu et al., PREPARATION AND CHARACTERIZATION OF NANOCRYSTALLINE POWDERS OF CUPROUS-OXIDE BY USING GAMMA-RADIATION, Materials research bulletin, 29(4), 1994, pp. 377-383
The gamma-radiation method has been firstly used to prepare nanocrysta
lline powders of cuprous oxide from cupric sulfate aqueous solution in
the presence of CH3COOH/CH3COONa buffer pair. X-ray powder diffractio
n reveals that the product is single phase of cuprous oxide. Electron
microscopy shows that the average particle size of cuprous oxide prepa
red is about 14 nm. Influences of experimental conditions on particle
size of cuprous oxide and the mechanism of the formation of cuprous ox
ide are discussed.