DIACYLATION OF ACTIVATED OLEFINS PROMOTED BY ELECTROCHEMICALLY GENERATED NO3-CENTER-DOT

Citation
T. Shono et al., DIACYLATION OF ACTIVATED OLEFINS PROMOTED BY ELECTROCHEMICALLY GENERATED NO3-CENTER-DOT, Tetrahedron letters, 35(24), 1994, pp. 4161-4164
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
24
Year of publication
1994
Pages
4161 - 4164
Database
ISI
SICI code
0040-4039(1994)35:24<4161:DOAOPB>2.0.ZU;2-S
Abstract
It has been found in this study that an acyl radical is formed by the reaction of an aldehyde with a radical NO3. generated by the anodic ox idation of NO3- and the reaction of this acyl radical with activated o lefins lead to the formation of a diacylated compound.