ON THE MECHANISM OF ASYMMETRIC DIHYDROXYLATION (AD) OF ALKENES

Authors
LOHRAY BB BHUSHAN V NANDANAN E
Citation
Bb. Lohray et al., ON THE MECHANISM OF ASYMMETRIC DIHYDROXYLATION (AD) OF ALKENES, Tetrahedron letters, 35(24), 1994, pp. 4209-4210
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
24
Year of publication
1994
Pages
4209 - 4210
Database
ISI
SICI code
0040-4039(1994)35:24<4209:OTMOAD>2.0.ZU;2-8
Abstract
H-1 NMR studies on bis(9-O-dihydroquinidinyl)terephthalate (DHQD(2)-TP ) with various concentrations of osmium tetroxide and trans-2-hexene r eveal that OsO4 is bound to both the quinuclidine moieties of DHQD(2)- TP but only one or the bound OsO4 reacts with alkenes in the AD proces s.