STEREOSELECTIVE ADDITION OF SILYL ENOL ETHERS TO ALPHA-FERROCENYLCARBENIUM IONS

Citation
Cj. Richards et al., STEREOSELECTIVE ADDITION OF SILYL ENOL ETHERS TO ALPHA-FERROCENYLCARBENIUM IONS, Tetrahedron letters, 35(24), 1994, pp. 4215-4218
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
35
Issue
24
Year of publication
1994
Pages
4215 - 4218
Database
ISI
SICI code
0040-4039(1994)35:24<4215:SAOSEE>2.0.ZU;2-4
Abstract
1-Ferrocenylalcohols are readily converted into their corresponding al pha-ferrocenylcarbenium tetrafluoborate salts. These react cleanly wit h silyl enol ethers to give alkylated products with up to 6:1 selectiv ity for the anti diastereoisomer.