REGIOSELECTIVITY STUDIES BY SELECTIVE DETECTION OF LONG-RANGE HETERONUCLEAR COUPLINGS FROM THE SDEPT-1D METHOD

Authors
PARELLA T SANCHEZFERRANDO F VIRGILI A
Citation
T. Parella et al., REGIOSELECTIVITY STUDIES BY SELECTIVE DETECTION OF LONG-RANGE HETERONUCLEAR COUPLINGS FROM THE SDEPT-1D METHOD, Magnetic resonance in chemistry, 32(6), 1994, pp. 343-347
Citations number
7
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
32
Issue
6
Year of publication
1994
Pages
343 - 347
Database
ISI
SICI code
0749-1581(1994)32:6<343:RSBSDO>2.0.ZU;2-C
Abstract
Some regiosomers formed by palladium(0)-catalysed allylation of severa l ambident heterocyclic nucleophiles, among others, were easily distin guished in very short spectrometer times by selective polarization tra nsfer via DEFT from well resolved protons to long-range coupled carbon s using the SDEPT-1D experiment. This pulse sequence was also analysed in terms of the product operator formalism. These structural elucidat ions can provide useful information about the regioselectivity in thes e reactions.