PULSED-FIELD GRADIENT SPIN-ECHO NMR MEASUREMENT OF WATER DIFFUSION-COEFFICIENT IN THICKENING AND GELLING AGENTS - GUAR GALACTOMANNAN SOLUTIONS AND PECTIN GELS
E. Brosio et al., PULSED-FIELD GRADIENT SPIN-ECHO NMR MEASUREMENT OF WATER DIFFUSION-COEFFICIENT IN THICKENING AND GELLING AGENTS - GUAR GALACTOMANNAN SOLUTIONS AND PECTIN GELS, Cellular and molecular biology, 40(4), 1994, pp. 569-573
The Pulsed Field Gradient Spin-Echo (PFG-SE) method was used to study
the diffusional properties of water in guar galactomannan solutions an
d in highly methyl-esterified (HDE) pectin solutions and gels. The dif
fusion coefficient of water in the non-gelling galactomannan system wa
s the same than that of pure water and independent on polymer concentr
ation, despite of a strong increase in viscosity. In the two-component
gelling system, pectin-sucrose, the diffusion coefficient of water wa
s lower than in the pure state, and decreasing as a function of the co
ncentration of both constituents. A normalized diffusion coefficient,
D-gel/D-suc, was defined to discriminate the effect of the gelation pr
ocess on water diffusion, and it showed a clear dependence on the exte
nt of network formation. Unrestricted diffusion was evidenced in all c
ases.