ELECTROOXIDATION OF HCOOH, CH2O, AND CH3OH AT PLATINUM MODIFIED WITH THE ADSORPTION PRODUCTS OF ORGANIC-SUBSTANCES

Authors
SPITSYN MA ANDREEV VN
Citation
Ma. Spitsyn et Vn. Andreev, ELECTROOXIDATION OF HCOOH, CH2O, AND CH3OH AT PLATINUM MODIFIED WITH THE ADSORPTION PRODUCTS OF ORGANIC-SUBSTANCES, Russian electrochemistry, 29(4), 1993, pp. 597-601
Citations number
13
Categorie Soggetti
Electrochemistry
Journal title
Russian electrochemistry → ACNP
ISSN journal
10703276
Volume
29
Issue
4
Year of publication
1993
Pages
597 - 601
Database
ISI
SICI code
1070-3276(1993)29:4<597:EOHCAC>2.0.ZU;2-Q
Abstract
The influence of preadsorbed monolayers of organic compounds on the el ectrooxidation of HCOOH, CH2O, and CH3OH was studied at platinized pla tinum. The adsorption products of benzene, aniline, paraphenylenediami ne, and nitrobenzene accelerated the oxidation of HCOOH and CH2O but i nhibited the oxidation of CH3OH. The effect of the adsorbed substances strongly depended on the substituents (and number of substituents) in the benzene ring of aromatic compounds. Possible reasons for these ef fects were discussed.