VIBRATIONAL SPECTROSCOPIC STUDY OF THE HYPOPHOSPHITE AND PHOSPHITE ANIONS, H2PO2- AND HPO(3)2-, AND OF THEIR DEUTERIATED ANALOGS IN THE SOLID-STATE AND IN AQUEOUS-SOLUTION

Authors
BICKLEY RI EDWARDS HGM KNOWLES A TAIT JKF GUSTAR RE MIHARA D ROSE SJ
Citation
Ri. Bickley et al., VIBRATIONAL SPECTROSCOPIC STUDY OF THE HYPOPHOSPHITE AND PHOSPHITE ANIONS, H2PO2- AND HPO(3)2-, AND OF THEIR DEUTERIATED ANALOGS IN THE SOLID-STATE AND IN AQUEOUS-SOLUTION, Spectrochimica acta. Part A: Molecular spectroscopy, 50(7), 1994, pp. 1277-1285
Citations number
12
Categorie Soggetti
Spectroscopy
Journal title
Spectrochimica acta. Part A: Molecular spectroscopy → ACNP
ISSN journal
05848539
Volume
50
Issue
7
Year of publication
1994
Pages
1277 - 1285
Database
ISI
SICI code
0584-8539(1994)50:7<1277:VSSOTH>2.0.ZU;2-O
Abstract
A full vibrational spectroscopic study of sodium hypophosphite, sodium phosphite and their deuteriated analogues has been made. The vibratio ns characteristic of the hypophosphite anion have been assigned and th e presence of a previously unreported band has been established for th e Raman spectrum of the aqueous solution. The first Raman study of deu teriated sodium phosphite has been undertaken and a full vibrational a ssignment is given.