T. Karanfil et al., IMPACTS OF DISSOLVED-OXYGEN ON THE SORPTION OF HUMIC SUBSTANCES AND THE SUBSEQUENT INHIBITION OF O-CRESOL UPTAKE BY GRANULAR ACTIVATED CARBON, Water research, 28(7), 1994, pp. 1673-1678
The impacts of dissolved oxygen (DO) on the sorption of natural and mo
del humic substances by granular activated carbon (GAC) were investiga
ted. Among five substances tested, the sorptions of only two, polymale
ic acid (PMA) and peat humic acid, were affected by the presence of DO
. The uptake of the target compound o-cresol on virgin GAC and on GAC
preloaded with PMA under oxic and anoxic conditions was also examined.
The oxic and anoxic preloading conditions had similar effects on subs
equent o-cresol reactions under both oxic and anoxic sorption conditio
ns. A reduction of approximately 20% in o-cresol uptake observed under
anoxic conditions by GAC preloaded under each condition is attributed
to a decrease in the adsorption capacity of the GAC by preloading. In
the presence of oxygen, however, an observed reduction of about 45% i
n o-cresol uptake by preloaded GAC appears to result from a combinatio
n of decreased adsorption and inhibited o-cresol polymerization.