BIS[(TERT-BUTYLAMIDO-DIMETHYLSILYL)CYCLOP ENTADIENYL]ZIRCONIUM, (T-C4H9N-SIME2-C5H4)2ZR, A SPIRANOID ZIRCONIUM ACYCLIC COMPOUND

Authors
BOHME U THIELE KH
Citation
U. Bohme et Kh. Thiele, BIS[(TERT-BUTYLAMIDO-DIMETHYLSILYL)CYCLOP ENTADIENYL]ZIRCONIUM, (T-C4H9N-SIME2-C5H4)2ZR, A SPIRANOID ZIRCONIUM ACYCLIC COMPOUND, Journal of organometallic chemistry, 472(1-2), 1994, pp. 39-41
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
472
Issue
1-2
Year of publication
1994
Pages
39 - 41
Database
ISI
SICI code
0022-328X(1994)472:1-2<39:BE(>2.0.ZU;2-J
Abstract
Independent of the molar ratio of the starting materials tylamido-dime thylsilyl)cyclopentadienyl]zirconium, (t-C4H9N-SiMe2-C5H4)2Zr, is form ed as a spiranoide zirconacyclus by reaction of ZrCl4 - 2THF with [t-C 4H9N-SiMe2-C5H4]Li2. The constitution was elucidated by means of H-1 a nd C-13 NMR spectroscopy.