SYNTHESIS, SPECTRUM AND SINGLE-CRYSTAL STRUCTURE OF A PEROXOVANADIUM COMPLEX OF NITRILOTRIACETATE LIGAND WITHOUT WATER OF CRYSTALLIZATION, K2[VO(O2)NTA]

Authors
WEI YG ZHANG SW HUANG GQ SHAO MC
Citation
Yg. Wei et al., SYNTHESIS, SPECTRUM AND SINGLE-CRYSTAL STRUCTURE OF A PEROXOVANADIUM COMPLEX OF NITRILOTRIACETATE LIGAND WITHOUT WATER OF CRYSTALLIZATION, K2[VO(O2)NTA], Polyhedron, 13(10), 1994, pp. 1587-1591
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
10
Year of publication
1994
Pages
1587 - 1591
Database
ISI
SICI code
0277-5387(1994)13:10<1587:SSASSO>2.0.ZU;2-N
Abstract
Crystals of the formula K2[VO(O2)NTA] with NTA = nitrilotriacetate hav e been prepared and characterized by IR and single-crystal X-ray diffr action methods. The structure of the anion of the complex shows that t he vanadium atom has a distorted pentagonal bipyramidal environment su rrounded by one oxo group, one peroxo group, three oxygen atoms and on e nitrogen atom from the NTA ligand.