STUDY OF THE LINKAGE ISOMERIZATION PROCESS IN HEXACYANOMETALLATES

Authors
REGUERA E BERTRAN JF NUNEZ L
Citation
E. Reguera et al., STUDY OF THE LINKAGE ISOMERIZATION PROCESS IN HEXACYANOMETALLATES, Polyhedron, 13(10), 1994, pp. 1619-1624
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
13
Issue
10
Year of publication
1994
Pages
1619 - 1624
Database
ISI
SICI code
0277-5387(1994)13:10<1619:SOTLIP>2.0.ZU;2-P
Abstract
The linkage isomerism in several transition metal hexacyanometallates was studied by Mossbauer, IR and XRD techniques. Ferrous chromicyanide and manganicyanide transform into Cr3+ ferrocyanide and Mn2+ ferrocya nide, respectively, through an unstable intermediate ferric salt produ ced by the mean of an electron transfer which reduces the inner cation to Cr(II) and Mn(II).