RING-OPENING COPOLYMERIZATION OF [2.2]PARACYCLOPHANE-1,9-DIENE (PCPDE) AND CYCLOOCTENE (COE) - A ROUTE TO SOLUBLE PRODUCTS WITH P-PHENYLENEVINYLENE SEQUENCES

Authors
THORNCSANYI E KRAXNER P HAMMER J
Citation
E. Thorncsanyi et al., RING-OPENING COPOLYMERIZATION OF [2.2]PARACYCLOPHANE-1,9-DIENE (PCPDE) AND CYCLOOCTENE (COE) - A ROUTE TO SOLUBLE PRODUCTS WITH P-PHENYLENEVINYLENE SEQUENCES, Journal of molecular catalysis, 90(1-2), 1994, pp. 15-20
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis → ACNP
ISSN journal
03045102
Volume
90
Issue
1-2
Year of publication
1994
Pages
15 - 20
Database
ISI
SICI code
0304-5102(1994)90:1-2<15:RCO[(>2.0.ZU;2-T
Abstract
Cyclooctene (COE) and [2.2] paracyclophane-1,9-diene (PCPDE) can be co polymerized via ring-opening metathesis polymerization (ROMP) with wel l-defined tungsten carbene. Distribution of p-phenylenevinylene units occurs statistically in manner of Bernoulli. Copolymers with higher co ntent of PCPDE ( > 5%) show physical properties influenced by p-phenyl enevinylene sequences.