CROSS-METATHESIS OF SOME FUNCTIONALIZED OLEFINS WITH CYCLOOLEFINS ANDBICYCLOOLEFINS CATALYZED BY WCL6-SILICON-CONTAINING COCATALYST SYSTEMS

Authors
BESPALOVA NB BOVINA MA SERGEEVA MB OPPENGEIM VD ZAIKIN VG
Citation
Nb. Bespalova et al., CROSS-METATHESIS OF SOME FUNCTIONALIZED OLEFINS WITH CYCLOOLEFINS ANDBICYCLOOLEFINS CATALYZED BY WCL6-SILICON-CONTAINING COCATALYST SYSTEMS, Journal of molecular catalysis, 90(1-2), 1994, pp. 21-27
Citations number
16
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis → ACNP
ISSN journal
03045102
Volume
90
Issue
1-2
Year of publication
1994
Pages
21 - 27
Database
ISI
SICI code
0304-5102(1994)90:1-2<21:COSFOW>2.0.ZU;2-V
Abstract
Homogeneous catalysts WCl6-1,1,3,3-tetramethyl-1,3-disilacyclobutane a nd WCl6-dihydrodiphenylsilane allow cross-metathesis of cycloolefins ( cyclopentene, cyclooctene) and norbornene with ethyl-4-pentenoate, all yl cyanide, allyltrimethylsilane. Self-metathesis of functionalized ol efins with two unconjugated carbon-carbon bonds takes place with high yields and selectivity.