STEADY-STATE AND PULSE-RADIOLYSIS OF TRIETHYLSILANE IN CYCLOHEXANE WITH PRODUCT ANALYSIS

Authors
GETOFF N RITTER A SCHWORER F BAYER P
Citation
N. Getoff et al., STEADY-STATE AND PULSE-RADIOLYSIS OF TRIETHYLSILANE IN CYCLOHEXANE WITH PRODUCT ANALYSIS, Radiation physics and chemistry, 44(5), 1994, pp. 491-498
Citations number
14
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Radiation physics and chemistry → ACNP
ISSN journal
0969806X
Volume
44
Issue
5
Year of publication
1994
Pages
491 - 498
Database
ISI
SICI code
0969-806X(1994)44:5<491:SAPOTI>2.0.ZU;2-Y
Abstract
The radiation induced major final products originating in the absence and in the presence of 0.1-1.0 mol dm-3 triethylsilane (R3SiH) in deox ygenated cyclohexane were determined. Similar experiments were perform ed in solutions saturated with N2O. In addition to this, pulse radioly sis of R3SiH/cyclohexane was performed. The obtained spectroscopic and kinetic data of the saline transients are compared with those previou sly reported in methanol solution and in pure R3SiH. Based on the expe rimental data a reaction mechanism is suggested.