EFFECT OF UNDERPOTENTIALLY DEPOSITED PB, TL, CD AND CU ADATOMS ON THEOXIDATION OF FORMALDEHYDE AT PD

Citation
G. Ritzoulis et N. Georgolios, EFFECT OF UNDERPOTENTIALLY DEPOSITED PB, TL, CD AND CU ADATOMS ON THEOXIDATION OF FORMALDEHYDE AT PD, Journal of electroanalytical chemistry [1992], 370(1-2), 1994, pp. 219-222
Citations number
14
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
370
Issue
1-2
Year of publication
1994
Pages
219 - 222
Database
ISI
SICI code
Abstract
The effect of underpotentially deposited Pb, Tl, Cd and Cu on the oxid ation of formaldehyde at a Pd electrode was studied. It was found that these adatoms inhibit formaldehyde oxidation since they block active sites on the electrode. Hence they prevent the formation of intermedia tes, which are necessary for the oxidation to occur.