YBa2Cu3O7 target was laser ablated, and the time-of-flight (TOF) distr
ibutions of Y, Y+, and YO in the resultant plasma were investigated as
functions of distance from the target and laser energy density using
emission spectroscopy. Up to a short distance from the target (congrue
nt-to 1.5 cm), TOF distributions show twin peaks for Y and YO, while o
nly single-peak distribution is observed for Y+. At greater distances
(>1.5 cm) all of them exhibit single-peak distribution. The twin peaks
are assigned to species corresponding to those generated directly/in
the vicinity of target surface and to those generated from collisional
/recombination process.