Hard carbon films were prepared by KrF excimer laser ablation from gra
phite and glassy carbon targets for different power densities (1 x 10(
8)-3.5 x 10(9) W cm-2), Substrate temperatures T(s) (from room tempera
ture to 300-degrees-C) and deposition rates. Optical and electrical pr
operties, Raman spectra, microhardness and morphology of the layers an
d time-of-flight (TOF) and resonant ionization spectroscopy of particl
es ablated from targets were studied. The best film properties were ob
tained for high densities and low T(s). In TOF spectra the ions of C+,
C2+, C++ and C3+ were identified.