TI-OET BOND-CLEAVAGE IN THE REACTION OF TI(OET)4 WITH MANGANESE CARBONYL HYDRIDE - THE NEW HETEROBIMETALLIC COMPLEX [TI3(OET)6(MU-2-OET)3(MU-3-OET)2]-([MN(CO)5])

Authors
BELYI AA KUZNETSOV VF BLUMENFELD AL
Citation
Aa. Belyi et al., TI-OET BOND-CLEAVAGE IN THE REACTION OF TI(OET)4 WITH MANGANESE CARBONYL HYDRIDE - THE NEW HETEROBIMETALLIC COMPLEX [TI3(OET)6(MU-2-OET)3(MU-3-OET)2]-([MN(CO)5]), Russian chemical bulletin, 42(8), 1993, pp. 1300-1303
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
42
Issue
8
Year of publication
1993
Pages
1300 - 1303
Database
ISI
SICI code
1066-5285(1993)42:8<1300:TBITRO>2.0.ZU;2-O
Abstract
Titanium ethoxide, which is trimeric in organic solvents, reacts with HMn(CO)5 to eliminate ethanol and to form a heterobimetallic complex. The cationic part of the latter contains three titanium atoms bound by mu2- and mu3-OEt bridging groups.