The adsorption properties of the new carbon materials, sibunites, whic
h are mesoporous samples with a developed surface of pores, were studi
ed. The isotherms of the adsorption of benzene vapor were determined t
o estimate the porous structure of these materials. The principal meth
ods for calculating the parameters of the porous structure of sibunite
s were analyzed. The application of the BET equation even in the prese
nce of a small number of micropores can distort the results, therefore
the most suitable method for estimating the surface of mesopores is o
ne that is based on the Dubinin-Zaverina equation. The estimation of t
he surface of sibunites using water vapor adsorption is demonstrated.