ADSORPTION PROPERTIES AND POROUS STRUCTURE OF NEW CARBON MATERIALS

Citation
Ns. Polyakov et al., ADSORPTION PROPERTIES AND POROUS STRUCTURE OF NEW CARBON MATERIALS, Russian chemical bulletin, 42(8), 1993, pp. 1308-1312
Citations number
11
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
42
Issue
8
Year of publication
1993
Pages
1308 - 1312
Database
ISI
SICI code
1066-5285(1993)42:8<1308:APAPSO>2.0.ZU;2-C
Abstract
The adsorption properties of the new carbon materials, sibunites, whic h are mesoporous samples with a developed surface of pores, were studi ed. The isotherms of the adsorption of benzene vapor were determined t o estimate the porous structure of these materials. The principal meth ods for calculating the parameters of the porous structure of sibunite s were analyzed. The application of the BET equation even in the prese nce of a small number of micropores can distort the results, therefore the most suitable method for estimating the surface of mesopores is o ne that is based on the Dubinin-Zaverina equation. The estimation of t he surface of sibunites using water vapor adsorption is demonstrated.