KINETICS OF THE MEDIATORY REDUCTION OF GEM-DICHLOROCYCLOPROPANES

Citation
Vv. Yanilkin et al., KINETICS OF THE MEDIATORY REDUCTION OF GEM-DICHLOROCYCLOPROPANES, Russian chemical bulletin, 42(8), 1993, pp. 1340-1343
Citations number
3
Categorie Soggetti
Chemistry
Journal title
ISSN journal
10665285
Volume
42
Issue
8
Year of publication
1993
Pages
1340 - 1343
Database
ISI
SICI code
1066-5285(1993)42:8<1340:KOTMRO>2.0.ZU;2-T
Abstract
The effect of the nature of organic electron transfer agents and of Pt (II), Pd(II), Rh(II), Co(II), Ni(II), Cu(II), Cr(III), Mn(II), Ti(II), V(III), Zn(II), and Ag(I) metal ions on the kinetics of the homogeneo us reduction of gem-dichlorocyclopropanes has been studied. Pt(II), Pd (II), Ph(III), Co(II), and Ni(II) ions accelerate this process, V(III) ana Ag(I) ions exert practically no effect on the reduction rate, and the rest of the metal ions exhibit inhibitor properties.